This activity explains the reaction of sodium carbonate and sodium hydrogen carbonate with acids, taken from chapter 2, Acids, Bases, and Salts.
How do Metal Carbonates and Metal Hydrogen Carbonates React with Acids?
Aim of the activity
To
observe the reaction of carbonates and bicarbonates with acid
Material used
1. Sodium
carbonate
2. Sodium
hydrogen carbonate
3. Dilute
hydrochloric acid
4. Lime
water
5. Test
tubes
6. Dropper
7. Delivery
tube
8. Cork
9. Test
tube stand
Procedure
We
take two test tubes and label them as A and B. Now we take about 0.5 g of sodium
carbonate (`Na_2CO_3`) in test A and about 0.5 g of sodium hydrogen carbonate
(`NaHCO_3`) in test tube B.
After that, we add
about 2 mL of dilute `HCl` to both the test tubes and observe the changes.
Now we pass the gas produced in each case through lime
water (calcium hydroxide solution)
Observation
Test tube |
Substance used |
After adding `HCl` |
Effect on lime water |
A |
`Na_2CO_3` |
Vigorous effervescence |
Lime water turns milky |
B |
`NaHCO_3` |
less Vigorous effervescence |
Lime water turns milky |
Explanation
1. Carbon dioxide gas is produced in both reactions.
`NaCO_3 + 2HCl → 2NaCl + H_2O + CO_2`
`NaHCO_3 + HCl → NaCl + H_2O + CO_2`
2. When `CO_2` is passed through lime water, an insoluble substance, calcium carbonate, is
formed, so the solution turns milky.
Ca(OH)2(aq)
+ CO2(g) → CaCO3(s) + H2O(I)
When the gas is passed in excess, calcium hydrogen
carbonate is formed and turns milky.
CaCO3(s) + CO2(g) → H2O(I)
→ Ca(HCO3)2(aq)
Conclusion
All acids react
with metal carbonates and metal hydrogen carbonates to form water
and the corresponding salt and `CO_2` gas
Frequently Asked Questions
1. Why
does lime water turn milky in this activity?
Answer – `CO_2` reacts with lime water to form an insoluble
calcium carbonate, so the solution appears milky.
2. In
which test tube more vigorous reaction take place?
Answer – The test tube A shows the vigorous reaction
because sodium carbonate reacts vigorously with `HCl`.
3. What
is the chemical formula of lime water?
Answer – `Ca(OH)_2`
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