In this article, we will learn about the properties of homologous series belonging to carbon and its compounds.
But first, we must know what is a homologous series?
You will find the following topics
1. What
is a homologous series?
2. Properties
of homologous series
3. Examples of homologous series
4. Questions
on homologous series
5. Quiz
on homologous series
What is a homologous series?
The series of organic compounds or carbon compounds
having similar functional groups and similar chemical properties is called a
homologous series.
Properties of homologous series
1. All
members of a homologous series can be prepared by the same method.
2. The
members of a homologous series have the same functional group.
3. There
is a difference of 1 carbon and 2
hydrogen atoms.
4. The
molecular formula of any two successive members of a homologous series differs
by a `-CH_2` unit.
Example
`CH_4` and `C_2H_6` differ by `-CH_2`
5. The
molecular masses of any two adjacent members of a homologous series differ by
14u.
Example
Molecular mass
of `CH_4`= 12×1+4×1=16u
Molecular mass
of `C_2H_6` = 12×2+6×1=30u
Difference =
30-16=14u
6. All
the members of a homologous series show similar chemical properties.
7. Physical
properties of members of a homologous series are graded with an increase in
molecular mass.
8. All
the members of a homologous series can be represented by a general formula.
Example
Alkane – `C_nH_(2n+2)`
Alkene
- `C_nH_(2n)`
Alkanol - `C_nH_(2n+1)OH`
9. Generally, the first member of a homologous series shows different behaviour from the
rest of the members.
Important homologous series on the basis of functional groups (General formula of homolgous series)
Example of homologous series
Homologous series of alkanes
Name |
Chemical formula |
Methane |
`CH4` |
Ethane |
`C2H6` |
Propane |
`C3H8` |
Butane |
`C4H10` |
Homologous series of alkenes
Name |
Chemical formula |
Ethene |
`C2H4` |
Propene |
`C3H6` |
Butene |
`C4H8` |
Pentene |
`C5H10` |
Homologous series of alkynes
Name |
Chemical formula |
Ethyne |
`C2H2` |
Propyne |
`C3H4` |
Butyne |
`C4H6` |
Pentyne |
`C5H8` |
Homologous series of alcohols
Name |
Chemical formula |
Methanol |
`CH3OH` |
Ethanol |
`C2H5OH` |
Propanol |
`C3H7OH` |
Butanol |
`C4H9OH` |
Homologous series of aldehydes
Name |
Chemical formula |
Methanal |
`HCHO` |
Ethanal |
`CH3CHO` |
Propenal |
`C2H5CHO` |
Butanal |
`C3H7CHO` |
Homologous series of carboxylic acids
Name |
Chemical formula |
Methanoic acid |
`HCOOH` |
Ethanoic acid |
`CH3COOH` |
Propanoic acid |
`C2H5COOH` |
Butanoic acid |
`C3H7COOH` |
Homologous series of ketone
Name |
Chemical formula |
Propanone |
`CH3COCH3` |
Butanone |
`CH3CH2COCH3` |
Pentanone |
`CH3CH2COCH2CH3` |
Hexanone |
`CH3CH2CH2COCH2CH3` |
Quiz
More Topics
FAQs
1. What is the general formula for the
homologous series that includes ethene?
Ans - `C_nH_(2n)`
2. To what homologous series does butane
belong?
Ans – Butane belongs
to alkanes
3. What
is the difference in the molecular formula of any two successive members of a
homologous series?
Ans - Two
successive members of a homologous
series by -`CH_2`.
4. What
is the difference between molecular masses of two adjacent members of a
homologous series?
Ans – The molecular masses of two adjacent members of
a homologous series differ by 14u.
5. Why
do all members of a homologous series show similar chemical properties?
Ans – Because all members of a homologous series have
similar functional groups.
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