We will discuss the definition of catalyst, types of catalysts, and examples of catalysts in this article.
1. Definition of catalyst
2. Types of catalysts with examples
3. Properties of catalyst
4. Factors affecting the action of catalysts
1. Definition of catalyst
Those substances which change the
velocity or speed of a chemical reaction but remain unchanged during the
reaction are called catalysts. This phenomenon is known as catalysis.
2. Types of catalysts with examples
Catalysts can be classified on the basis of the following factors
i. On the basis of the physical state
ii. On the basis of action
i. On the basis of physical state: - catalysts are of two types on the basis of physical state
a. Homogenous catalysts
b. Heterogenous catalysts
a. Homogenous catalyst: - When catalyst, reactants, and products are in the same physical state in a chemical reaction, then the catalyst is known as homogenous catalyst and the reaction is known as homogenous catalysis.
`CH_3COOCH_{3(l)} +H_2O_{(l)} \overset{HCl_(aq)}{\rightarrow}CH_3COOH_{(aq)}+CH_3OH_{(aq)}`
In the reaction reactants, catalysts and products are in a liquid(aqueous) state.
b. Heterogenous catalyst: - When catalyst, reactants, and products are in different physical states then the catalyst is called a heterogenous catalyst and the reaction is known as heterogenous catalysis.
`N_{2(g)} + 3H_2(g) \overset{Fe(s)}{\rightarrow}2NH_{3(g)}`
ii. On the basis of action: - Catalysts are of the following types on the basis of their action
a. Positive catalyst
b. Negative
catalyst
c. Auto
catalyst
d. Bio
catalyst
a. Positive
catalyst: - Catalysts that increase the rate of chemical reactions are called positive
catalysts.
`2KClO_3\overset{MnO_2}{\rightarrow}2KCl + 3O_2`
`2SO_2 + O_2\overset{V_2O_5}{\rightarrow}2SO_3`
`MnO_2` and `V_2O_5` increase
the rate of reaction so they are positive catalysts.
b. Negative
catalyst: - Catalysts that decrease the rate of a chemical reaction is called negative
catalysts.
`2H_2O \overset{glycol}{\rightarrow} 2H_2O + O_2`
`2CHCl_3\overset{C_2H_5OH}{\rightarrow}2COCl_2 + 2HCl`
Glycol and ethanol
decrease the rate of reaction, so they are negative catalysts.
c. Auto
catalyst: - When the product formed in a chemical reaction itself acts as a catalyst
and increases the speed of the chemical reaction is called an auto catalyst.
`CH_3COOC_2H_5 + H_2O→ CH_3COOH+ C_2H_5OH`
The reaction is slow in the beginning but when some amount of acetic acid (`CH_3COOH`)is formed, the rate of reaction increases, and acetic acid acts as an auto catalyst.
d. Bio
catalyst: - The substance which is used to increase the speed of biochemical reactions
is called a biocatalyst. Enzymes are biocatalysts.
Enzymes are complex
nitrogenous organic compounds and are specific for particular biochemical
reactions.
`NH_2CONH_2+ H_2O \rightarrow \overset{urease}{\rightarrow}2NH_3 + CO_2`
Urease is an enzyme
that acts as a biocatalyst.
3. Properties
of catalyst
i.
Catalysts
only change the rate of reaction.
ii.
Catalysts do not take part in the reaction
and remain unchanged during the reaction.
iii.
Small amount of catalyst is sufficient.
iv.
A single catalyst does not catalyze all
the chemical reactions in the same manner.
v.
Catalysts do not initiate or start a
chemical reaction.
vi.
In reversible reactions, catalysts affect the rate of both forward and backward reactions in the same manner.
4. Factors affecting catalysts
The activity of catalyst can be affected by the following factors
i. Catalyst promotor
ii. Catalyst inhibitor
iii. Temperature
i. Catalyst promotor: - Those substances which when added to a catalyst in a chemical reaction increase the activity of the catalyst are called catalyst promotors. These substances only increase the activity of the catalyst.
`2N_2 + 3H_2 \overset{Fe(Mo)}{\rightarrow}2NH_3`
Fe acts as a catalyst
in the reaction and molybdenum acts as a catalyst promotor.
`\text{Vegetable oil} + H_2 \overset{Ni(Cu)}{\rightarrow} \text{vegetable ghee}`
Ni acts as a catalyst and Cu is a catalyst promotor.
ii. Catalyst inhibitor: - Those substances which when added to a catalyst in a chemical reaction decrease the activity of the catalyst are called catalyst inhibitors.
`N_2+ 3H_2 \overset{Fe(CO)}{\rightarrow} 2NH_3`
Iron acts as a catalyst and carbon monoxide acts as a catalyst inhibitor.
iii. Change in temperature also affect the activity of catalysts.
Related Topics
1. What happens during a chemical reaction
FAQs
1. Define catalyst.
Ans. A catalyst is a substance that changes the rate of a chemical reaction.
2. How can the activity of catalysts be affected?
Ans. The activity of catalysts can be affected by catalyst promotor, catalyst inhibitor, and temperature.
3. How do catalysts work?
Ans. The catalyst appears in the complete mechanism of a chemical reaction but does not appear in the reactant side and product side.it only changes the speed of the reaction.
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