If you are looking for a preparation method for sodium hydroxide, and its uses, then this is for you.
This topic belongs to Chapter 2 Acids, bases, and salts class 10 science NCERT book.
Table of Contents
2.Properties of Sodium hydroxide
3. Preparation methods of Sodium Hydroxide
6.
8.FAQs
Preparation Process of NaOH
What is Sodium Hydroxide?
Sodium hydroxide is a strong base and also an alkali.
Its common name is Caustic soda and its chemical formula is NaOH.
Properties of sodium hydroxide
1. It
is a white crystalline solid.
2. It
is highly corrosive
3. It
is odourless
4. It
is soluble in water
5. Inorganic compound
6. Its melting point is 591K
7. Its crystals are hygroscopic
Preparation methods of Sodium hydroxide
Sodium hydroxide can be prepared by following methods
1: Castner-Kellner Process
2: Chlor-Alkali
Process
In this topic, we will discuss the preparation of sodium hydroxide by the chlor-alkali process.
Chlor-alkali Process (Class 10)
Raw materials:
- Sodium chloride (NaCl) and water
Principle:
- Sodium hydroxide is prepared by electrolysis of a solution of sodium chloride(brine).
Preparation of brine:
- Saturated solution of sodium chloride is called brine. So NaCl is mixed in
water to produce brine.
Electrolysis of brine
Electrolysis of a concentrated solution of sodium chloride(brine)
is done in an electrolytic cell which is known as a ‘Diaphragm cell’. When an electric
current is passed through the brine, ionization of NaCl takes place.
Chloride ions move towards the anode and sodium ions move
towards the cathode.
Chlor-alkali Process |
Chlor alkali process equation
`2NaCl + 2H_2O →2NaOH_{(aq)} + Cl_{2(g)} + H_{2(g)}`
The above chlor -alkali equation is carried out as
follows
Ionization of NaCl
`NaCl(aq) → 2Na^+ +
2Cl^-`
(at Cathode) (at anode)
Sodium chloride gets ionized into sodium and chloride
ions
Ionization of `H_2O`
`2H_2O → 2H^+ + 2OH^-`
(at Cathode) (at anode)
Water gets decomposed into hydrogen and hydroxyl ions
Electrochemical changes
At cathode `2H^+
+2e^- → H_{2(g)}`
Hydrogen ions are reduced to hydrogen gas by accepting
electrons.
At anode `2Cl^- → Cl_2 + 2e^-`
Chloride ions are oxidized to chlorine gas by losing
electrons.
In solution `2Na^+ + 2OH^- → 2NaOH`
Sodium ions and hydroxyl ions accumulate in the solution. On
evaporation. Sodium hydroxide is obtained.
`2NaCl + 2H_2O →2NaOH_{(aq)} + Cl_{2(g)} + H_{2(g)}`
The products of the chloralkali process are
i). chlorine gas
ii). Hydrogen gas
iii). Sodium hydroxide
Uses of Sodium Hydroxide(Caustic soda)
The following are the most important uses of sodium hydroxide
1. In the manufacturing of soap and detergents
2. In
degreasing metal sheets and rods
3. In
textile industries
4. In the synthesis of artificial fibers
5. In
paper making
6. As
a laboratory reagent
Uses of Chlorine gas
1. In the manufacturing of chloroform, bleaching powder, HCl
2. For water treatment
3. In the manufacturing of PVC
4. In manufacturing pesticides
5. In making CFC
Uses of hydrogen gas
1. In
making vegetable ghee (hydrogenation process)
2. In
manufacturing ammonia
3. As
fuel used in rockets
4. In
making margarine
Safety Precautions
1. Always
wear goggles, a lab coat
2. Protect
eyes, skin
3. Avoid
direct contact with NaOH
Quiz
Important questions
Q1. Why sodium hydroxide is called caustic soda?
Ans.- The word ‘Caustic’ means burning or corrosive
nature and it burns living tissues so sodium hydroxide is called caustic soda.
Q2. Why sodium hydroxide is called an alkali?
Ans. - The base
which is soluble in water is called alkali and sodium hydroxide is soluble in
water.
Q3. What is brine?
Ans. – A saturated sodium chloride solution is called brine.
Q4. Why mixing of NaOH in water an exothermic reaction?
Ans. – When sodium hydroxide is mixed in water, it
dissociates into sodium ions and hydroxyl ions and heat is liberated so this is
an exothermic reaction.
Q5. What type of
compound is sodium hydroxide?
Ans. – Sodium hydroxide is an inorganic ionic compound
Q6. What is formed when zinc reacts with sodium
hydroxide?
Ans. – When zinc reacts with sodium hydroxide, sodium
zincate, and hydrogen gas are produced.
`Zn + 2NaOH → Na_2ZnO_2 + H_2`
Q7. Why sodium hydroxide preparation method is called the chlor alkali method?
Ans- In this process, one product is chlorine and the other is sodium hydroxide which is an alkali so this process is called the chlor alkali method.
Q8. How is NaOH prepared from sodium chloride?
Ans - When an electric current is passed through an aqueous solution
of sodium chloride, it decomposed to form sodium hydroxide. Chlorine and
hydrogen gases are also produced.
FAQs (Frequently Asked Questions)
1. What is the formula for sodium hydroxide?
Ans – NaOH
2. The reaction between sodium hydroxide and
hydrochloric acid is considered what type of reaction?
Ans -
The reaction between sodium hydroxide and hydrochloric acid is a neutralization
reaction.
3. What type of solution is formed when solid
sodium hydroxide (NaOH) is dissolved in water?
Ans –
Sodium hydroxide is an ionic substance when it is dissolved in water, it gets
dissociates into ions and forms an ionic alkaline solution.
4. What is the molecular weight of sodium hydroxide (NaOH)?
Ans – The molecular weight of sodium hydroxide is 40.
5. What is the molar mass of sodium hydroxide,
NaOH?
Ans - 39.997
g/mol
Related Topics
1. Physical Properties of Metals
3. Preparation of Washing Soda
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